2025 NCAAF Top 25 Teams: Archvillains and Key Matchups to Watch
Explore the archvillains and key matchups for the top 25 NCAAF teams in the 2025 season. Discover the players, coaches, and teams that could define the year.

2025 NCAAF Top 25 Teams: Archvillains and Key Matchups
As the 2025 college football season approaches, the top 25 teams are gearing up for intense rivalries and critical matchups. Here’s a breakdown of the archvillains and key games that could shape the season:
1. Penn State: Ryan Day
Penn State’s James Franklin has struggled against Ohio State’s Ryan Day, losing six straight games. With a veteran squad, the Nittany Lions aim to reverse their fortunes in a pivotal November showdown.
2. Clemson: LaNorris Sellers
Clemson’s defense will be tested against South Carolina’s elusive quarterback, LaNorris Sellers, who nearly derailed their season last year.
3. Texas: Oklahoma
The Longhorns face their annual test against Oklahoma in Dallas, a game that could have major implications for their SEC and national championship aspirations.
4. Georgia: Alabama
Georgia’s Kirby Smart has struggled against Alabama, and this year’s matchup in Athens could be crucial for playoff positioning.
5. Ohio State: Sherrone Moore
Michigan’s Sherrone Moore has become a thorn in Ohio State’s side, leading the Wolverines to four straight victories over the Buckeyes.
6. LSU: Daytime Home Games
LSU’s Tiger Stadium is known for its electric night games, but day games in the sweltering September heat could be a challenge.
7. Notre Dame: Miami
Notre Dame’s Marcus Freeman faces a tough early-season test against Miami, led by transfer quarterback Carson Beck.
8. Oregon: Ohio State
Oregon’s Dan Lanning will look to avoid a repeat of last year’s Rose Bowl drubbing by Ohio State, though a rematch could only occur in the playoffs.
9. Alabama: Vanderbilt
Alabama seeks revenge against Vanderbilt after a shocking loss last season, which derailed their campaign.
10. BYU: Utah
The “Holy War” between BYU and Utah is always intense, and this year’s matchup could have major Big 12 title implications.
11. Illinois: Max Klare
Illinois must contain Ohio State’s Max Klare, who had a breakout performance against them last season.
12. Arizona State: Regression
Arizona State faces the challenge of avoiding regression after a strong 2024 season, a common issue in the Big 12.
13. South Carolina: LSU
South Carolina looks to avenge last year’s heartbreaking loss to LSU, which cost them a playoff bid.
14. Iowa State: Kansas State
The season opener in Dublin between Iowa State and Kansas State could be a de facto elimination game for Big 12 title hopes.
15. SMU: TCU
SMU and TCU face off in what could be their last Iron Skillet game for the foreseeable future, adding extra heat to the rivalry.
16. Texas Tech: Baylor
Texas Tech’s Joey McGuire faces his former team, Baylor, in a critical Big 12 matchup.
17. Indiana: UCLA
Indiana’s Curt Cignetti must contend with UCLA, which features former Hoosiers coach Tino Sunseri and player Jamier Johnson.
18. Kansas State: Iowa State
Kansas State’s season opener against Iowa State will be a crucial test for their offense and turnover management.
19. Florida: Georgia
Florida’s Billy Napier faces a tough test against Georgia, which has dominated the rivalry under Kirby Smart.
20. Michigan: Ohio State
Michigan’s Sherrone Moore aims to extend their winning streak against Ohio State, but the Buckeyes are eager for revenge.
21. Miami: Syracuse
Miami looks to avenge last year’s loss to Syracuse, which kept them out of the ACC championship game.
22. Louisville: Kentucky
Louisville’s Jeff Brohm aims to continue their recent success against Kentucky in a heated rivalry game.
23. Texas A&M: Steve Sarkisian
Texas A&M faces a tough test against Texas and Steve Sarkisian, who has revitalized the Longhorns.
24. Ole Miss: Mississippi State
Ole Miss must contend with the dreaded cowbells of Mississippi State in their annual rivalry game.
25. Oklahoma: Texas
Oklahoma faces Texas in the Cotton Bowl, a game that could define their season in the SEC era.